20.–25. Sept. 2026
Münster
Europe/Berlin Zeitzone

Geochemical preservation of organic-walled dinocysts during extreme climatic events through experimental and paleontological approaches via infrared spectroscopy and mass spectrometry

22.09.2026, 14:45
45m
Fürstenberghaus

Fürstenberghaus

Poster Innovative approaches and cutting-edge techniques answer urgent questions in palaeobotany Poster session

Sprecher

Rahaf Ishkokani (Department of Geology, Ku Leuven Univeristy, and Blue Growth Research Lab, Gent University.)

Beschreibung

Dinoflagellates play a key role in marine ecosystems and are known for producing organic-walled cysts (dinocysts), which are valuable for reconstructing paleoceanic and climatic variability. Analyses using Attenuated Total Reflection Micro–Fourier Transform Infrared Spectroscopy (ATR–micro FTIR) have identified the molecular structure of dinosporin, the primary constituent of the dinocyst wall. Dinosporin is a stable, carbohydrate-based biomacromolecule that may exhibit variable contributions from certain functional groups (Meyvisch et al., 2023).

Recently, we assessed the compositional stability of dinosporin during early diagenetic processes associated with the fossilization of modern dinocysts fossilization of modern dinocysts, across shallow to deep-marine settings spanning the Upper Pleistocene to Holocene. Our findings demonstrate that dinosporin remains largely unaltered, reiterating its remarkable biomolecular stability. However, the integrity of dinosporin under extreme climatic perturbations remains poorly constrained.

Therefore, we are investigating the response of dinocyst wall chemistry to global warming by combining experimental and paleontological approaches. Cultures of living dinoflagellates are subjected to controlled environmental stressors analogous to major geological events, namely the Paleocene–Eocene Thermal Maximum (~56 Ma) and the Late Maastrichtian Warming Event (~66 Ma). In parallel, fossilized dinocysts from these intervals will be analysed.

A combination of spectrochemical techniques, including ATR–micro FTIR, and mass spectrometric methods will be employed to characterize molecular modifications, trace-element incorporation, and adaptive responses in cyst wall chemistry. Integrating experimental and fossil evidence will improve our understanding of dinocyst resilience to rapid climate change and contribute to the development of novel biomarkers for reconstructing past and future environmental variability.

Autor

Rahaf Ishkokani (Department of Geology, Ku Leuven Univeristy, and Blue Growth Research Lab, Gent University.)

Co-Autoren

Pjotr Meyvisch (Johns Hopkins University) Aurélie Penaud (geo-ocean lab, université de bretagne occidentale, plouzane, france) Kenneth Neil Mertens (Ifremer, Concarneau, France) Ilias Semmouri (Blue Growth Research Lab, Gent University, Gent, Belgium) Jana Asselman (blue growth research lab, gent university, gent, belgium) Johan Vellekoop (Department of Geology, Ku Leuven Univeristy and Directorate Earth and History of Life, Royal Belgian Institute of Natural Sciences.)

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